Well, quite obviously, the best guitarplaying is on Politics Of Ecstasy, the best solo is from the halftime-bridge in seven tongues of god, or in 42147.
Dreaming Neon Black is a great cd, but the guitarplaying wasn't quite as 'virtuoso', and didn't make me go 'Holy fuck!! This guy is amazing!!'. Dreaming Neon Black was simpler than Politics, but it is a much better 'album', it is put to together better than poe.
I don't really know why it was called 'Rhythm Guitarist' poll, that was just FUCKING dim. It is all shared between the guitarists i beleive.
Poe is best guitaring. In Memory/DNB are the best albums as far as 'songwriting' goes.