It's crazy to think that i've been down those roads and even climbed on that glacier (i think, can't remember exactly)
Volcanic lightning isn't very well understood, it's thought to be caused by the different compounds in the ash being ionised differently due to the heat. The different compounds have different aerodynamic properties which causes them to separate as the cloud moves with the hot air rising and the wind. This separation leads a HUGE potential difference. If the potential difference is great enough then the electricity arcs across the separation.