After watching the album title announcement video, I decided to do more research into what the title means, and its connection to an older song. An older song, according to Matt, that comes from Infected Nations. Now, I don't exactly remember how I got to the conclusion I came up with so bear with me.
I started at Hundred Wrathful Deities, which (I think) is a reference to the hundred peaceful and wrathful deities of hindu and buddhist religion.
http://www.rigpawiki.org/index.php?title=Hundred_peaceful_and_wrathful_deities
From there I can't exactly recall how I got to researching the Hindu god Shiva, but I did. Shiva has five forms (or faces) each representing something different. Earth, Wind, Fire, Water, and space.
http://en.wikipedia.org/wiki/Shiva#The_five_mantras
Now get this shit, SHIVA WEARS FIVE SERPENTS as ornaments.
I think I got it coach!