Between Heaven and Hell, definitely.
For Raintime:
Gotta have the opening song, Rainbringer. That was just incredible energy and a great way to kick things off.
Virgin Steele:
Didn't enjoy the set much, but the last song was really cool. Veni, Vici, Vidi, or whatever. Nice.
Redemption:
Sapphire. 'Nuff said.
Pagan's Mind:
Engimatic Mission. Through Osiris' Eyes will probably end up there, but we already have that on a PP DVD. I hope they do something a little more daring, like put New World Order on it.
Sonata Arctica:
San Sebastian. Their performance was pretty standard(I've seen them before), but San Sebastian was played with particular energy.
Threshold:
Pilot in the Sky of Dreams. Best Threshold song ever
Primal Fear:
Nuclear Fire. Brilliantly played that night. Woke me up.
After Forever:
Energize Me.
Jam:
Final Countdown was my favorite moment. I also loved Youth Gone Wild with Raintime's singer.