Female Fronted Bands

Oh this is easy....

LAKE OF TEARS - Neonai

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The female vocals on that are very sugary sweet, and yet the music is quite melancholic, so you get this cool blend of emotions. Really great album.
 
I forgot to mention Estatic Fear's second album ' a sombre dance.' It's fairly easy to find too (as opposed to the first one :erk: ).
 
I second a few of circus_brimstone's recos:

Stolen Babies
Aghora
To-Mera

Add:
Stream of Passion (top 5 for 2005 for me)
White Willow (especially their latest two)
After Forever (the first 2 only)
Moon of Steel
Echosilence (their latest EP - the demos were instrumental)
Elfonia (same singer as Stream of Passion, music isn't quite as tasty)
Brave